Picrate

Picrate

A picrate is a salt or an ester of picric acid (a 2,4,6-trinitrophenol). But it could also be an additional compound which picric acid forms with many aromatic hydrocarbons, aromatic amines, aliphatic amines, alkalines, and other compounds cite book
author = Smith, M. B.; March, J.
title = March's Advanced Organic Chemistry
publisher = John Wiley & Sons
date = 6th ed. 2007
pages = 118
id = ISBN 978-0-471-72091-1
] . These additional compounds are also called picrates even that they are not a salt of picric acid.

The picrate ion has yellow color. Many picrates are explosives, for example ammonium picrate (known as Dunnite). Some are used as primary explosives, namely lead picrate or potassium picrate which find their use as primers for cartridge ammunition. Ferrous picrate is used in some applications as a diesel fuel additive to achieve better mileage.

Picrates of some metals tend to be significantly more sensitive to impact and friction than picric acid itself (therefore storage of picric acid and mixtures containing it in containers made of these metals is strongly discouraged).

References


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  • picrate — [ pikrat ] n. m. • 1836; de picr(o) et suff. chim. ate 1 ♦ Chim. Sel de l acide picrique. Le picrate d ammonium est un explosif. 2 ♦ (1916; nom d un café 1882) Fam. Vin rouge de mauvaise qualité. Il « s envoyait viande et légume avec ses deux… …   Encyclopédie Universelle

  • Picrate — Pi crate, n. (Chem.) A salt of picric acid. [1913 Webster] …   The Collaborative International Dictionary of English

  • picrate — [pik′rāt΄] n. a salt or ester of picric acid, usually highly explosive and sensitive to shock …   English World dictionary

  • Picrate — Les picrates sont les sels de l acide picrique et ont pour formule C6H2N3O7. L acide picrique est un explosif, d abord produit par l industrie des colorants et qui a été le plus utilisé dans les obus lors de la Première Guerre mondiale. En se… …   Wikipédia en Français

  • PICRATE — n. m. T. de Chimie Nom générique des sels que forme l’acide picrique. Le picrate de potasse est une substance explosive d’une grande force …   Dictionnaire de l'Academie Francaise, 8eme edition (1935)

  • picrate — pikratas statusas T sritis chemija apibrėžtis Pikro rūgšties druska arba jos ir aromatinio junginio kompleksas. atitikmenys: angl. picrate rus. пикрат …   Chemijos terminų aiškinamasis žodynas

  • Picrate d'ammonium —  Ne doit pas être confondu avec Dunite. Picrate d ammonium Picrate d ammonium …   Wikipédia en Français

  • picrate — picrated, adj. /pik rayt/, n. Chem. a salt or ester of picric acid. [1865 70; PICR(IC ACID) + ATE2] * * * …   Universalium

  • picrate — noun any salt or ester of picric acid …   Wiktionary

  • picrate — A salt of picric acid. * * * pic·rate pik .rāt n a salt or ester of picric acid * * * pic·rate (pikґrāt) any salt of picric acid …   Medical dictionary

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